反应条件
1: trimethylaluminum; (5E,9E)-6,10,14-trimethylpentadeca-5,9,13-trien-1-yne With methyl aluminoxane; rac-ethylenebis(1-indenyl)zirconium(IV) chloride in toluene
T=20°C; Negishi carboalumination; 8 h;
2: 2-chloromethyl-5,6-dimethoxy-3-methyl-[1,4]benzoquinone With NiCl2((PPh3)P)2; n-butyllithium in tetrahydrofuran
T=-20°C; 2 h;
参考文献
Lipshutz, Bruce H.; Butler, Tom; Lower, Asher
Journal of the American Chemical Society, 2006 , vol. 128, # 48 p. 15396 - 15398
