in neat (no solvent)
under N2; Al-compd. added slowly over a period of 2 h to Sb-compd. at 0°C with stirring, warmed slowly to room temp., stirred for 4 h, heated for 12 h at 120°C;; monitored by NMR, fractional distn., Al-compd. isolated by sublimation;;
参考文献
Thomas, C. J.; Krannich, L. K.; Watkins, C. L.
Polyhedron, 1993 , vol. 12, p. 89 - 94
1: trimethylaluminum With titanium(IV) isopropylate; (S)-2-hydroxy-3-phenylpropionic acid in tetrahydrofuran; toluene
T=22°C; 2.5 h;
2: benzaldehyde in tetrahydrofuran; toluene
T=22°C; 2.5 h; Title compound not separated from byproducts;
in benzene-d6
byproducts: toluene; under N2; in NMR tube; AlMe3 in C6D6 added to soln. of Ni complex in C6D6; not isolated; monitored by (1)H NMR spectra;
参考文献
Stapleton, Russell L.; Chai, Jianfang; Taylor, Nicholas J.; Collins, Scott
Organometallics, 2006 , vol. 25, # 10 p. 2514 - 2524
