in neat (no solvent) BaO reacts with CHI3 under formation of BaI2 after some days; CHI3 decomposites under formation of I2 and HI at influence of light;;
1: methyl malonic acid diethylester With sodium hydride in diethyl ether; mineral oil 2.5 h; Reflux; 2: triiodomethane in diethyl ether; mineral oil 36 h; Reflux; 3: With potassium hydroxide in ethanol; water 24 h; Reflux;
参考文献
Kulyk, Svitlana; Dougherty, William G.; Kassel, W. Scott; Zdilla, Michael J.; Sieburth, Scott M.
Organic Letters, 2011 , vol. 13, # 9 p. 2180 - 2183
1: With 1,4-bis(dibenzyloxy)butane; diethylzinc in 1,2-dichloro-ethane 0.0833333 h; 2: With water-d2; D2SO4 (sulfonic acid-d2) in 1,2-dichloro-ethane Further stages.;
参考文献
Charette, Andre B.; Gagnon, Alexandre; Fournier, Jean-Francois
Journal of the American Chemical Society, 2002 , vol. 124, # 3 p. 386 - 387
