1: mercapto acetic acid ethylester With sodium salt of phosphorous acid in N,N-dimethyl-formamide
Metallation; 0.25 h;
2: monobromotrifluoromethane With hydroxymethanesulfinic acid sodium salt in N,N-dimethyl-formamide
Alkylation; P=3375.27 Torr; 8 h;
参考文献
Anselmi, Elsa; Blazejewski, Jean-Claude; Tordeux, Marc; Wakselman, Claude
Journal of Fluorine Chemistry, 2000 , vol. 105, # 1 p. 41 - 44
para-dicyanobenzene; tetraethylammonium tetrafluoroborate in N,N-dimethyl-formamide
electrolysis; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Medebielle, Maurice; Oturan, Mehmet Ali; Pinson, Jean; Saveant, Jean-Michel
Journal of Organic Chemistry, 1996 , vol. 61, # 4 p. 1331 - 1339
tetraethylammonium tetrafluoroborate; para-dicyanobenzene in N,N-dimethyl-formamide
(indirect electrochemical reduction of the perfluoroalkyl halide in the presence of imidazolate anion); Yield given. Yields of byproduct given;
2-picoline; Na2S2O5; sulfur dioxide; zinc in N,N-dimethyl-formamide
T=65°C; P=2250.2 - 3750.3 Torr; 3 h; other pyrrole-derivatives;
参考文献
Tordeux, Marc; Langlois, Bernard; Wakselman, Claude
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 8 p. 2293 - 2299
