zinc in pyridine
T=20°C; P=1500.1 - 3000.2 Torr; 4 h;
参考文献
Tordeux, Marc; Francese, Catherine; Wakselman, Claude
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 7 p. 1951 - 1957
in N,N-dimethyl-formamide
byproducts: Me2NCH(CF3)O(1-), fluoroform; Electrolysis; inert atmosphere; in DMF/TMEDA, Zn-anode, stainless steel cathode, Bu4NBr supporting electrolyte, 0.3 A, -15°C bubbling CF3Br; not isolated, reaction followed by (19)F-NMR spectroscopy;
参考文献
Grobe, Joseph; Hegge, Joachim
Zeitschrift fur Anorganische und Allgemeine Chemie, 2008 , vol. 634, # 11 p. 1975 - 1990
in further solvent(s)
byproducts: ZnBr2; Electrolysis; excess of CF3Br in N-methyl-2-pyrrolidone (NMP), sacrificial Zn anode, 1V, at room temp.; detd. by (19)F NMR studies;
参考文献
Grobe, Joseph; Hegge, Joachim
Zeitschrift fur Anorganische und Allgemeine Chemie, 2008 , vol. 634, # 11 p. 1975 - 1990
Dymov, B. P.; Skorobogatov, G. A.; Khripun, V. K.
Russian Journal of Physical Chemistry, 1991 , vol. 65, # 8 p. 1107 - 1112
Zhurnal Fizicheskoi Khimii, 1991 , vol. 65, p. 2085 - 2093
