2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
potassium γ-hydroxybutyrate in tetrahydrofuran-2-one T=200°C; P=11251.1 Torr; 6 h;
参考文献
Tosoh F-Tech, Inc.
Patent: EP1426351 A1, 2004 ;
Location in patent: Page 8 ;
反应条件
hydrogen; lt;(Ph3P)(Ph2P)RuH2-K+*diglymegt;2 in toluene T=90°C; P=4650.4 Torr; 20 h; Title compound not separated from byproducts;
参考文献
Grey, Roger A.; Pez, Guido P.; Wallo, Andrea; Corsi, Jeff
Journal of the Chemical Society, Chemical Communications, 1980 , # 16 p. 783 - 784
反应条件
trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; potassium tert-butylate; hydrogen in 1,4-dioxane T=40°C; P=7500.75 Torr; 16 h; GloveboxInert atmosphere; TimeConcentrationPressureTemperature;
参考文献
Zell, Thomas; Ben-David, Yehoshoa; Milstein, David
Angewandte Chemie - International Edition, 2014 , vol. 53, # 18 p. 4685 - 4689
Angew. Chem., 2014 , vol. 126, # 18 p. 4773 - 4777
反应条件
(K(1+))2lt;(Ph3P)3(Ph2P)Ru2H4gt;(2-)*2C6H14O3; hydrogen in toluene T=90°C; P=4650.4 Torr; 4 h; Yield given;
参考文献
Journal of the American Chemical Society, , vol. 103, # 25 p. 7536 - 7542
反应条件
trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate in 1,4-dioxane T=40°C; P=18751.9 Torr; 16 h; GloveboxInert atmosphere;
参考文献
Zell, Thomas; Ben-David, Yehoshoa; Milstein, David
Angewandte Chemie - International Edition, 2014 , vol. 53, # 18 p. 4685 - 4689
Angew. Chem., 2014 , vol. 126, # 18 p. 4773 - 4777
反应条件
trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate in 1,4-dioxane T=40°C; P=18751.9 Torr; 48 h; GloveboxInert atmosphere;
参考文献
Zell, Thomas; Ben-David, Yehoshoa; Milstein, David
Angewandte Chemie - International Edition, 2014 , vol. 53, # 18 p. 4685 - 4689
Angew. Chem., 2014 , vol. 126, # 18 p. 4773 - 4777
反应条件
trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate in 1,4-dioxane T=40°C; P=18751.9 Torr; 16 h; GloveboxInert atmosphere;
参考文献
Zell, Thomas; Ben-David, Yehoshoa; Milstein, David
Angewandte Chemie - International Edition, 2014 , vol. 53, # 18 p. 4685 - 4689
Angew. Chem., 2014 , vol. 126, # 18 p. 4773 - 4777
反应条件
trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate in 1,4-dioxane T=40°C; P=18751.9 Torr; 16 h; GloveboxInert atmosphere;
参考文献
Zell, Thomas; Ben-David, Yehoshoa; Milstein, David
Angewandte Chemie - International Edition, 2014 , vol. 53, # 18 p. 4685 - 4689
Angew. Chem., 2014 , vol. 126, # 18 p. 4773 - 4777
反应条件
trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate in 1,4-dioxane T=40°C; P=18751.9 Torr; 16 h; GloveboxInert atmosphere;
参考文献
Zell, Thomas; Ben-David, Yehoshoa; Milstein, David
Angewandte Chemie - International Edition, 2014 , vol. 53, # 18 p. 4685 - 4689
Angew. Chem., 2014 , vol. 126, # 18 p. 4773 - 4777
反应条件
trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate in 1,4-dioxane T=40°C; P=18751.9 Torr; 16 h; GloveboxInert atmosphere;
参考文献
Zell, Thomas; Ben-David, Yehoshoa; Milstein, David
Angewandte Chemie - International Edition, 2014 , vol. 53, # 18 p. 4685 - 4689
Angew. Chem., 2014 , vol. 126, # 18 p. 4773 - 4777
