2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
2,6-dimethylpyridine; ozone solvolytic rearrangements study; Mechanism;
参考文献
Lee, Choi Chuck; Wanigasekera, Dave
Canadian Journal of Chemistry, 1987 , vol. 65, p. 933 - 940
反应条件
water T=25°C; deuterium isotope effect; Product distributionRate constant;
参考文献
Shiner, V. J.; Tai, Jimmy J.
Journal of the American Chemical Society, 1981 , vol. 103, # 2 p. 436 - 442
反应条件
water T=25°C; deuterium isotope effect; Product distributionRate constant;
参考文献
Shiner, V. J.; Tai, Jimmy J.
Journal of the American Chemical Society, 1981 , vol. 103, # 2 p. 436 - 442
反应条件
pyridine T=90°C; 0.5 h; other fluorinated alcohols; hydride shift in cyclohexyl tosylate solvolysis; Product distribution;
参考文献
Schneider, H.-J.; Busch, Rainer
Journal of Organic Chemistry, 1982 , vol. 47, # 9 p. 1766 - 1769
反应条件
in water T=45°C; Solvolysis; Kinetics; TemperatureSolvent;
参考文献
Fujiyama, Ryoji; Alam, Md. Ashadul; Shiiyama, Aiko; Munechika, Toshihiro; Fujio, Mizue; Tsuno, Yuho
Journal of Physical Organic Chemistry, 2010 , vol. 23, # 9 p. 819 - 827
反应条件
potassium 2,2,2-trifluoroethoxide T=30°C; μ = 0.05 M with potassium trifluoroacetate; Rate constant;
参考文献
Xu, Yiying; Dietze, Paul E.
Journal of the American Chemical Society, 1993 , vol. 115, # 23 p. 10722 - 10727
反应条件
water in acetonitrile T=25°C; various composition of trifluoroethanol/ethanol; solvolytic reaction; role of nucleophilic and other solvation effects; product selectivity; Rate constant;
参考文献
Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha
Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659
反应条件
in water T=25°C; KineticsActivation energy;
参考文献
Gordon; Maskill
Journal of the Chemical Society, Perkin Transactions 2, 2001 , # 11 p. 2059 - 2062
反应条件
P=1.005 - 28.7 Torr; Irradiation; Product distributionKinetics;
参考文献
McAlpine, Robert D.; Evans, D. K.; Goodale, J. W.
Canadian Journal of Chemistry, 1983 , vol. 61, p. 1481 - 1486
反应条件
tert.-butylhydroperoxide; Ti-Al-β (H-form) in water T=90°C; 1.66667 h; var. of solvent/educt, cation exchanged catalyst; Product distribution;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 16 p. 1887 - 1888
