2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
tetraethylammonium bromide T=80°C; 5 h; Mechanism;
参考文献
Chemische Berichte, , vol. 115, # 2 p. 772 - 782
反应条件
1: With sodium hypochlorite; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; potassium bromide in acetonitrile T=20°C; pH=8 - 9; 48 h; 2: With sulfuric acid in water pH=1 - 2; 3: in methanol T=20°C; 1 h;
参考文献
Ignatowska, Jolanta; Shyshkov, Oleg; Zipplies, Tilman; Hintzer, Klaus; Roeschenthaler, Gerd-Volker
Journal of Fluorine Chemistry, 2012 , vol. 141, p. 35 - 40
反应条件
water T=25°C; deuterium isotope effect; Product distributionRate constant;
参考文献
Shiner, V. J.; Tai, Jimmy J.
Journal of the American Chemical Society, 1981 , vol. 103, # 2 p. 436 - 442
反应条件
water T=25°C; deuterium isotope effect; Product distributionRate constant;
参考文献
Shiner, V. J.; Tai, Jimmy J.
Journal of the American Chemical Society, 1981 , vol. 103, # 2 p. 436 - 442
反应条件
1: 2,2,2-trifluoroethanol With sodium hydride in tetrahydrofuran; mineral oil T=20°C; 0.5 h; 2: 2-Chloro-5-pyridinecarboxylic Acid Methyl Ester in tetrahydrofuran; acetonitrile; mineral oil T=70°C; 1.5 h;
参考文献
WO2010/146351 A1, ;
Page/Page column 57-58 ;
WO 2010/146351 A1
反应条件
tert.-butylhydroperoxide; Ti-Al-β (H-form) in water T=90°C; 1.66667 h; var. of solvent/educt, cation exchanged catalyst; Product distribution;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 16 p. 1887 - 1888
反应条件
toluene-4-sulfonic acid
参考文献
Air Reduction Co.
Patent: US2809218 , 1955 ;
反应条件
in water T=25°C; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 118, # 46 p. 11434 - 11445
反应条件
water T=25°C; var. trifluoroethanol/water ratios, other alcohols and 1-(4-methoxyphenyl)-3-methyl-3-butyl derivatives; Rate constantProduct distributionMechanism;
参考文献
Journal of the American Chemical Society, , vol. 118, # 46 p. 11434 - 11445
反应条件
water T=25°C; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 118, # 46 p. 11434 - 11445
