1: benzyl ethyl ether With Al tri-t-BuO- in benzene T=20°C; Oxidation; 72 h; 2: tert.-butylhydroperoxide With sulfuric acid in diethyl ether; water Hydrolysis; 3: benzyl methyl ether; aluminum isopropoxide With sulfuric acid in diethyl ether; water Etherification; Further byproducts given;
参考文献
Russian Journal of General Chemistry, , vol. 69, # 2 p. 257 - 262
[Fe(III)(tmp)]Cl in dichloromethane 24 h; Ambient temperatureother reaction partners, time, solvent, and temp.; other alkene; Product distributionMechanism;
参考文献
Journal of the American Chemical Society, , vol. 113, # 7 p. 2747 - 2753
pyridine; [Cu(bipy)2]+; oxygen in acetonitrile T=22°C; P=760 Torr; other methylenic hydrocarbons; other catalyst and oxygenating agent; also in absence of O2; kinetic isotope effect <K> investigation; Product distribution;
参考文献
Menage, Stephane; Collomb-Dunand-Sauthier, Marie-Noe.; Lambeaux, Claude; Fontecave, Marc
Journal of the Chemical Society, Chemical Communications, 1994 , # 16 p. 1885 - 1886
{Fe(tris(2-pyridylmethylamine))Cl2}ClO4 in acetonitrile T=25°C; var. Fe-tris(2-pyridylmethyl)amine complexes; other cycloalkanes and alkyl hydroperoxides; Product distributionMechanism;
参考文献
MacFaul, Philip A.; Arends, Isabella W. C. E.; Ingold, Keith U.; Wayner, Danial D. M.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1997 , # 2 p. 135 - 146
RuO2-FAU in acetone T=20°C; 5 h; Product distribution; Further Variations:Reagentsconcentration;
参考文献
Zhan, Bi-Zeng; White, Mary Anne; Pincock, James A.; Robertson, Katherine N.; Cameron, T. Stanley; Sham, Tsun-Kong
Canadian Journal of Chemistry, 2003 , vol. 81, # 6 p. 764 - 769
