反应条件
lithium aluminium tetrahydride; n-butyllithium in tetrahydrofuran; water under N2; n-BuLi in n-hexane added to soln. of thiophenol in TMEDA at 0°C; refluxed (2 h); Se added at 0°C; stirred (room temp.,6h); solvent removed; dissolved in THF; treated with LiAlH4(3 h), ice-cold water and then with Me2SnCl2 in H2O; stirred for 30 min at room temp.; extd. with CH2Cl2; dried with anhyd. Na2SO4; solvent removed under reduced pressure; purified by column chromy. (silica gel, CCl4-CHCl3); elem. anal.;
参考文献
Ogawa, Satoshi; Ohmiya, Tadahito; Kikuchi, Takamasa; Kawaguchi, Atsuko; Saito, Satoshi; Sai, Akihiko; Ohyama, Naomi; Kawai, Yasushi; Niizuma, Shigeya; Nakajo, Shiduko; Kimura, Takeshi; Sato, Ryu
Journal of Organometallic Chemistry, 2000 , vol. 611, # 1-2 p. 136 - 145
