in gaseous matrix Irradiation (UV/VIS); laser-ablated Ti atoms reacted with CCl4 in Ar during condensation at 8 K, irradiated; not isolated, detected by IR;
in gaseous matrix Kinetics; byproducts: CO; components mixt. (2.5, 10, 30 and 70 wt.-percent C)chlorination with Cl2/Ar (p(Cl2)=0.35 atm, total, flow 2.1 l/h NTP) at const. temp. in range of 733-1223 K; gravimetric monitoring;
in neat (no solvent) reaction at 570-620K; mechanism discussed; at lower temp. very slow reaction;;
参考文献
Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk, , p. 434 - 438
Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk, , # 4 p. 59 - 65
