in Petroleum ether dropwise addn. of soln. of TiCl4 in petroleum ether (40-60°C) to soln. of 1-trialkoxysilyl 2-phenylhydrazine (equimolar amts., 0 to -10°C, under dry nitrogen), ppt. filtered in a cold atm. of dry N2; washed, dried under reduced pressure; elem. anal.;
Yoshino et al.
Kogyo Kagaku Zasshi, 1954 , vol. 57, p. 898
Chem.Abstr., 1956 , p. 3294
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Cullinane et al.
Journal of the Chemical Society, 1954 , p. 3894
in chloroform-d1 react. of Bu3SnCH2CHCHCH3 with TiCl4 (1 equiv) at 30°C under complete and rapid formation of Bu3SnCl and a brown ppt. of the allyl titanium trichloride;
参考文献
Harston, Paul; Wardell, James L.; Marton, Daniele; Tagliavini, Giuseppe; Smith, Peter J.
Inorganica Chimica Acta, 1989 , vol. 162, p. 245 - 250
in diethyl ether byproducts: H2, KCl; under inert atm. soln. K(H2BC8H14) in Et2O was added dropwise to soln. TiCl4 in Et2O (5:1) and stirred at room temp. for 12 h; soln. was filtered and evapd. in vacuo, residue was dissolved in ether and kept at -30°C; elem. anal.;
参考文献
Ding, Errun; Du, Bin; Liu, Fu-Chen; Liu, Shengming; Meyers, Edward A.; Shore, Sheldon G.
Inorganic Chemistry, 2005 , vol. 44, # 13 p. 4871 - 4878
