air; hydrogen in gas
TiCl4 (liq.) evapd.; oxidized in a diffusion flame reactor contg. 5 concentric tubes; reactor with multipoint diffusion-type burner; flame configuration Ar+TiCl4/Ar/H2/O2/air;
参考文献
Jang, Hee Dong; Kim, Seong-Kil
Materials Research Bulletin, 2001 , vol. 36, # 3-4 p. 627 - 637
in gaseous matrix
gaseous TiCl4 carried by stream of Ar into quartz or alumina react. tube heated at 1100-1400°C, NH3 simultaneously introduced, react. allowed to proceed for 2 h; chem. and X-ray anal.;
参考文献
Saeki, Yuzo; Matsuzaki, Ryoko; Yajima, Akimasa; Akiyama, Masayo
Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 10 p. 3193 - 3196
drying at 773 K, exposure to SiCl4 at 473 K, passing through N2-flow, exposure to humid air at 473-773 K, heating at 473 K, repeating 6 times and ones with TiCl4; detd. by X-ray diffraction;
Goldfarb; Smorgonski
Chemische Berichte, 1936 , vol. 69, p. 1037
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1936 , p. 555
Chem. Zentralbl., 1938 , vol. 109, # I p. 1107
Goldfarb; Smorgonski
Chemische Berichte, 1936 , vol. 69, p. 1037
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1936 , p. 555
Chem. Zentralbl., 1938 , vol. 109, # I p. 1107
Shchegrov, L. N.
Trudy Ural'skogo Politekhnicheskogo Instituta im. S. M. Kirova, 1960 , # 96 p. 82 - 92
C. A., 1961 , p. 19424
Full Text Show Details
Gmelin Handbook: Cl: SVol.A, 10, page 12 - 13
air; water in water
byproducts: TiO2; reaction of TiCl4 with HNO3 in aq. soln. under formation of Cl2, TiO2 and NOCl; separation of Cl2; reaction of MnO2 with HNO3 and NOCl under formation of MnCl2; reaction of MnCl2 with HNO3 under formation of Cl2 and Mn(NO3)2; regeneration of MnO2, HNO3;;
参考文献
Gmelin Handbook: Cl: SVol.A, 7, page 9 - 10
Full Text Show Details
Chemical Foundation Inc.
Patent: US2732310 , 1956 ;
C. A., 1956 , p. 8228
