in neat (no solvent) Tm treated with iodine vapors in two-chamber quartz reactor according toGoryushkin, V. F., et al., Zh. Neorg. Khim., 1996, vol. 41, p. 1536; te mp. of chamber with I2 was 490 K; temp. of chamber with metal was elevated for 150 h to 1100 K; purified by vac. distn. at 1370 K and 0.5 Pa;
参考文献
Krokhina, A. G.; Andrachnikova, A. P.; Strekachinskii, A. B.; Krokhin, V. A.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1980 , vol. 25, p. 901 - 904
Zhurnal Neorganicheskoi Khimii, 1980 , vol. 25, p. 1624 - 1629
in ethylene glycol dimethyl ether absence of air and moisture; excess I2, stirring at room temp. for 48 h,filtration off of TmI3, repeated addn. of further DME, stirring and ref luxing to color change to green; solvent removal (vac., room temp.), recrystn. (DME, -10°C); elem.anal.;
参考文献
Bochkarev, Mikhail N.; Fedushkin, Igor L.; Fagin, Anatoly A.; Petrovskaya, Tatyana V.; Ziller, Joseph W.; Broomhall-Dillard, Randy N. R.; Evans, William J.
Angewandte Chemie (International Edition in English), 1997 , vol. 36, # 1-2 p. 133 - 135
Brueckner
Angewandte Chemie, 1927 , vol. 40, p. 974
Angewandte Chemie, 1928 , vol. 41, p. 228
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Schilow
Z. chim. Promysl., vol. 6, p. 538
Chem. Zentralbl., 1929 , vol. 100, # II p. 2658
in neat (no solvent) mixt. of metal and I2 was heated to the deflagration point of the mixt. in vac.; excess of I2 was evacuated, tube was filled with Ar, solidified metal part was removed, elem. anal.; metal triiodide was deposited on the wall of tube;
参考文献
Khoroshenkov; Petrovskaya; Fedushkin; Bochkarev
Zeitschrift fur Anorganische und Allgemeine Chemie, 2002 , vol. 628, # 3 p. 699 - 702
in neat (no solvent) 450°C, sealed glass tube; elem. anal.;
参考文献
Alexander, K. M.; Fairbrother, F.
Journal of the Chemical Society, 1949 , p. 2472 - 2476
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Brauer, G.
Handbuch der praeparativen anorganischen Chemie, 1. Aufl., Stuttgart 1954, S. 983
