in neat (no solvent, gas phase)
Kinetics; react. in a flowing-afterglow reactor, carrier gas Ar (flow rate 0.05 mol/min, 1.5 Torr, 50°C); not isolated;
参考文献
Zhang, Fu Min; Oba, D.; Setser, D. W.
Journal of Physical Chemistry, 1987 , vol. 91, # 5 p. 1099 - 1114
in sulfur dioxide
A soln. of I2 and AsF5 was stirred in SO2 at room temp. for 48 h, volatile components were slowly removed producing dark crystals, which form a red powder by grinding.; The red powder was dissolved in SO2, the crystals were obtained by slowly removal of the solvent.;
参考文献
Faggiani, R.; Gillespie, R. J.; Kapoor, R.; Lock, C. J. L.; Vekris, J. E.
Inorganic Chemistry, 1988 , vol. 27, p. 4350 - 4355
sugar charcoal in melt
redn. of ThO2 with sugar charcoal, reaction of melt with I2-vapor;;
参考文献
Gmelin Handbook: Th: MVol., 89, page 274 - 276
→
反应条件
in neat (no solvent, solid phase)
heating of the components in a sealed ampoule to 180°C (within 24 h) and annealing at 340°C for 2 days; sublimation at 540°C (high vac.) in a Ta vessel;
参考文献
Beck, H. P.; Schuster, M.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1993 , vol. 619, p. 690 - 694
