in water
byproducts: H20, NO2(1-), H(1+); product ratios depend on ratio hydroxylamine:periodate, pH is adjusted and kept constant with 0.2 M acetate buffer; iodide concn. detd. by a Orion iodide selective electrode and a SCE as reference electrode, iodine concn. detd. by spectrophotometry, nitrite concn. detd. by using Griess-Ilosovay reaction,;
参考文献
Rabai, Gyula; Epstein, Irving R.
Journal of Physical Chemistry, 1989 , vol. 93, # 22 p. 7556 - 7559
in epoxysulfonyl fluoride
N2-atmosphere; standing (1 d); not isolated, reaction followed by (31)P-NMR spectroscopy;
参考文献
Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 883 - 890
in sulfuric acid
dry N2-atmosphere; mixing equimolar amts. in 100 percent H2SO4 (room temp.); product mixt. not sepd., detd. by (31)P-NMR spectroscopy;
参考文献
Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1591 - 1594
in sulfuric acid
dry N2-atmosphere; mixing equimolar amts. in 100 percent H2SO4 (room temp.); product mixt. not sepd., detd. by (31)P-NMR spectroscopy;
参考文献
Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1591 - 1594
