Couturier
Bulletin de la Societe Chimique de France, 1890 , vol. <3>4, p. 31
Annales de Chimie (Cachan, France), 1892 , vol. <6>26, p. 455
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Fittig
Justus Liebigs Annalen der Chemie, 1860 , vol. 114, p. 58
1: 3-chloro-pyridine With n-butyllithium; diisopropylamine in diethyl ether T=-60°C; 0.75 h; 2: With tri-isopropoxy-borane in diethyl ether T=-60 - 10°C; 3: 2,3-dimethylbutane-2,3-diol With acetic acid in diethyl ether 4 h;
3-chloroprop-1-ene; trifluoroacetic acid; cobalt(II) dibromide in acetonitrile Zn dust (1.5 equiv., acid-activated) , CoBr2 (0.1 equiv.), stirred for 5min with allyl chloride (0.3 equiv.), a soln. of aryl halide (1 equiv.) and a soln. 1 equiv. of B compd. added at room temp., stirred for 30 mi n, tranesterificated with pinacol; hydrolized (NH4Cl), extd. (diethyl ether);
参考文献
Claudel, Stephanie; Gosmini, Corinne; Paris, Jean Marc; Perichon, Jacques
Chemical Communications, 2007 , # 35 p. 3667 - 3669
Et3N in dichloromethane byproducts: Et3NH-AlCl4; to borenium cation made in situ (in Schlenk, to soln. Et2N (CH2Cl2) added CatBCl, AlCl3; stirred) at 20°C arene added (CH2Cl2); excess Et3N added; pinacol added; stirred for 1 h;; (11)B (1H) NMR; volatiless remowed under vac; extracted (hexane); filtered through silica; removal of solvent;;
参考文献
Del Grosso, Alessandro; Singleton, Paul J.; Muryn, Christopher A.; Ingleson, Michael J.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 9 p. 2102 - 2106
