1: With hydrogen fluoride; chromium - based fluorination catalyst T=180°C; 2: With Cr and In on graphite catalyst T=180°C; 4 h; Inconel 600 type reactor; 3: With Cr on active alumina catalyst Inconel 600 type reactor; Product distribution / selectivity;
oxygen in neat (no solvent) other Radiation; (60)Co-γ-radiation of CF4 at 77K, formation of C2F6 and CF3OCF3;; yield of CF3OCF3 depending on O2-percentage; determination by ESR;;
1: (trifluoromethyl)-trimethylsilane With silver fluoride in N,N-dimethyl-formamide T=20°C; 0.333333 h; 2: With copper in N,N-dimethyl-formamide 4 h; 3: n-dodecyl iodide in N,N-dimethyl-formamide
参考文献
Journal of Fluorine Chemistry, , vol. 133, p. 67 - 71
