in various solvent(s)
T=153°C; 124 h; variation of conditions, other solvent t-BuPh; also with triphenylmethyl bromide and addition of D2O; MechanismProduct distribution;
参考文献
Huszthy, Peter; Kajtar-Peredy, Maria; Lempert, Karoly; Hegedues-Vajda, Judit
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1992 , # 3 p. 347 - 354
in acetonitrile
byproducts: triethanolamine hydrobromide; under dry N2; mixt. boiled (81°C, 3 h); hot soln. decanted vac.-evapd. (20-100 mm, 30-35°C) until crystn. set in; ether added; solid 1-(triphenylmethyl)germatrane isolated; ppt. of chlorogermatrane obtained by evapn. of filtrate (40-50°C, 40mm); Ph3CH isolated from soln.; PMR;
参考文献
Gar, T. K.; Khromova, N. Yu.; Tandura, S. N.; Mironov, V. F.
Journal of General Chemistry USSR (English Translation), 1983 , vol. 53, p. 1619 - 1626
Zhurnal Obshchei Khimii, 1983 , vol. 53, p. 1800 - 1807
in chloroform
stoich., mixed, pptd. for 240 h at 20°C; ppt. filtered, dried (vac.), filtrate evaptd.(vac.), residue washed (ether), IR, NMR;
参考文献
Kalinkin, M. I.; Markosyan, S. M.; Parnes, Z. N.; Kursanov, D. N.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 9 p. 1759 - 1761
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , vol. 30, # 9 p. 2141 - 2143
