1: 1-hydroxyindan With iPr2NCHEt2; (-)-Tetramisole in tetrahydrofuran T=-78°C; 0.5 h; Molecular sieveInert atmosphereResolution of racemate; 2: triphenyl-silyl chloride in tetrahydrofuran T=-78°C; 1 h; Inert atmosphereResolution of racemate; optical yield given as percent eeenantioselective reaction;
in neat (no solvent) isolation from atmosphere; stirring (0 - 20°C, 5 - 10 min); mixt. not sepd.; IR spectroscopy;
参考文献
Gordetsov, A. S.; Skobeleva, S. E.; Vostokov, I. A.; Egorochkin, A. N.
Journal of General Chemistry USSR (English Translation), 1980 , vol. 50, p. 515 - 519
Zhurnal Obshchei Khimii, 1980 , vol. 50, p. 632 - 637
