in neat (no solvent)
thermal decompn. of HClO4 on hot Pt at higher temp.;; detection by mass spectroscopy;;
参考文献
Heath, G. A.; Majer, J. R.
Transactions of the Faraday Society, 1964 , vol. 60, p. 1783 - 1791
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Gmelin Handbook: Cl: SVol.B2, 54, page 431 - 433
Nikitina, Z. K.; Rosolovskii, V. Ya.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1980 , vol. 25, p. 715 - 718
Zhurnal Neorganicheskoi Khimii, 1980 , vol. 25, p. 1285 - 1290
in perchloric acid
Kinetics; excess hypophosphite, 0.1-2.5 M HClO4, I=2.5 M (NaClO4), 35-55°C (H3PO5 generated in situ or prepd. on treatment of K4P2O8 with 1.0 M HClO4 at 45°C for 4 h); not isolated, reaction followed by titrimetry of peroxo-group;
参考文献
Kapoor, Surinder; Gupta, Yugul K.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 862 - 865
Kozlov, Y. A.; Blokhin, V. V.; Shurukhin, V. V.; Mironov, V. E.
Zhurnal Fizicheskoi Khimii, 1973 , vol. 47, p. 1343 - 1344
Zhurnal Fizicheskoi Khimii, 1973 , vol. 47, p. 2386 - 2387
