phenyl-magnesium bromide in dichloromethane Ge compd. and equimol. amt. of SnCl4 reacted in CH2Cl2 at room temp. to give the SnCl3 compd.; SnCl3 compd. reacted in THF at - 78 °C with 5 mol. amts. of PhMgBr;
参考文献
Takeda, Takeshi; Tamada, Yoshitake; Yamaguchi, Jun-ichi; Fujiwara, Tooru
Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan), 1994 , p. 301 - 306
in not given 35-40°C, according to S. D. Rosenberg, A. J. Gibbons Jr., J. Am. Chem. Soc., 79 (1957) 2138; crude product was fractionated under reduced pressure; purity of the product was checked by a GC anal. using He as carrier gas (addnl. peaks due to (CH2=CH)4Sn and (CH2=CH)2SnCl2 were present);
参考文献
Vincent, E.; Verdonck, L.; Naessens, L.; Kelen, G. P. van der
Journal of Organometallic Chemistry, 1984 , vol. 277, # 2 p. 235 - 244
