oxygen in neat (no solvent) oxygen saturated with SnCl4 at 60°C was led through a fluidized bed of MoO3 for 7 h at 430°C or in a reactor with a stream of oxygen or air carrying SnCl4 for 3-6 h at 500°C;
参考文献
Buiten, J.
Polyhedron, 1988 , vol. 7, p. 585 - 586
magnesium in not given Sonication; mixt. of tin derivative, Mg turnings, solvent (Et2O or THF) and few drops of organic bromide was sonicated (ultrasound, 47 kHz, 300W), soln. of organic bromide was added; washed with brine, extd. with Et2O, dried over MgSO4, evapd. in vac., column chromy. (neutral alumina or silica gel, petroleum ether);
参考文献
Journal of Organometallic Chemistry, , vol. 694, # 15 p. 2368 - 2374
AlCl3 in neat (no solvent) byproducts: C2H5SiCl3; heated at 110-145°C for 9 h; AlCl3 filtered off; filtrate distd.;
参考文献
Motsarev, G. V.; Chernyshev, E. A.; Rozenberg, V. R.; Inshakova, V. T.; Zetkin, V. I.
Journal of General Chemistry USSR (English Translation), 1983 , vol. 53, p. 985 - 988
Zhurnal Obshchei Khimii, 1988 , vol. 53, p. 1111 - 1114
AlCl3 in neat (no solvent) byproducts: CH3SiCl3; heated for 1 h to 110°C; stirred for 2 h; heated to 120°Cand then at 140°C for 9-10 h; AlCl3 filtered off; filtrate distd.; elem. anal.;
参考文献
Motsarev, G. V.; Chernyshev, E. A.; Rozenberg, V. R.; Inshakova, V. T.; Zetkin, V. I.
Journal of General Chemistry USSR (English Translation), 1983 , vol. 53, p. 985 - 988
Zhurnal Obshchei Khimii, 1988 , vol. 53, p. 1111 - 1114
