KCl; NaCl; HCl in water Kinetics; Electrochem. Process; 24°C, normal atm. pressure, pH 1.5; electrodeposited on graphite at -880, -920, -960 and -1020 mV; dried (P2O5); not isolated; SEM, EDS, BET;
H3BO3 in water Electrochem. Process; electrodeposited in conventional three-electrode cell; electrolyte prepd. of by dissolved of ZnCl2 and H3BO3 in H2O; pulsed electrodeposition carried out at .+-.80 mAcm**-2 of c.d.; deposited charge density fixed at 179.2 mCcm**-2; XRD; SEM;
参考文献
He, Huichao; Xiao, Peng; Zhang, Yunhuai; Jia, Yichao; Yang, Yannan; Qiao, Zhengyang
Journal of Alloys and Compounds, 2012 , vol. 522, p. 63 - 68
in melt melting together anhydrous ZnCl2 and Mn powder (vac.) at 800°C for 24 h until all the ZnCl2 was reduced to Zn metal (immicible layer); on cooling, polycrystalline MnCl2 was recovered which was separate fromthe slug of the solid Zn metal;
参考文献
Jacobsen, Stuart M.; Guedel, Hans U.; Smith, W. Ewen
Inorganic Chemistry, 1987 , vol. 26, p. 2001 - 2005
in ethanol Electrolysis; electrolysis of ThCl4 soln. in 97percent ethanol in presence of formaldehyde, hydroxylammonium chloride and 10percent alc. ZnCl2 soln. at Pt-electrodes (11-15V, c.d. 0.1 A/cm*cm);; product mixt. contg. 57percent Th obtained;;
