NaOH in methanol; water amine was added to soln. of NaOH in MeOH; cooled at 10°C in ice bath; CS2 was added dropwise with stirring; bath removed; aq. soln. of ZnCl2 was slowly added with stirring; filtered; residue washed (H2O); dried in vac. at room temp.; elem. anal.;
参考文献
Memon, Ashfaq A.; Afzaal, Mohammad; Malik, Mohammad A.; Nguyen, Chinh Q.; O'Brien, Paul; Raftery, Jim
Dalton Transactions, 2006 , # 37 p. 4499 - 4505
in toluene under N2 atm. to suspn. ZnCl2 in toluene ZnEt2 was added and heated in sealed tube to 70-75°C for 72 h; hot soln. was filtered, Znet2 was evapd. in vacuo, soln. was cooled slowly to -26°C; elem. anal.;
参考文献
Guerrero, Antonio; Hughes, David L.; Bochmann, Manfred
Organometallics, 2006 , vol. 25, # 6 p. 1525 - 1527
