反应条件
sodium tetrahydroborate in methanol; benzene under nitrogen, molar ratio ditelluride:Pt-complex=1:1, to dilute methanolic NaBH4 soln. was added a C6H6/MeOH (1:3, v/v) soln. of dianisylditelluride, benzene suspn. of Pt2Cl2(μ-Cl)2(((CH3)3C)2PC(CH3)2CH2)2 was added, stirred for 6h; solvents evapd. in vac., dissolved in C6H6, filtered off NaCl, concd. in vac., MeOH (contg. >5percent C6H6) was added, crystn. was initiated by scratching with a spatula, filtered off, washed with MeOH, dried, recrystn. from a C6H6/hexane mixt., elem. anal.;
参考文献
Jain, Vimal K.; Kannan, S.
Journal of Organometallic Chemistry, 1991 , vol. 418, # 2-3 p. 349 - 357
