in chloroform; water mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaCl, water and chloroform was vigorously stirred under reflux at 56°C, 2-2.5 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;
in neat (no solvent) shaking of Na, CaCl2 and NaCl in a closed supremax-tube for 30 min at 500-810°C until equilibrium; heating for 15 min at the same temperature; chilling; examination of the equilibrium;; seperation of the saltfree metal- and the saltphase under ether;;
参考文献
Lorenz, R.; Winzer, R.
Z. Anorg. Chem., 1929 , vol. 181, p. 193 - 202
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Gmelin Handbook: Ca: MVol.B2, 80, page 448 - 451
in water Kinetics; byproducts: H2O, Cl(1-); HCl was introduced into aq. soln. of Pd-complex, 0.5 M acid concn. and 15-30 °C, 0.7-4.0 M chloride concn.,;
参考文献
Surovtseva; Orlov; Morozova; Krylov; Belov
Kinetics and Catalysis, 2006 , vol. 47, # 6 p. 855 - 857
in sulfuric acid Kinetics; exposure of NaCl with 96 wtpercent H2SO4 (0.5:1 H2SO4:NaCl) in dry bag; storage in desiccator for several days; exposure to environment of 100percent rel. humidities for 40 min; not isolated, detn. by Raman spectroscopy;
参考文献
Zangmeister; Pemberton
Journal of the American Chemical Society, 2000 , vol. 122, # 49 p. 12289 - 12296
