in tetrachloromethane
under N2; SbCl5 reacted with Me3SbS (molar ratio 1:1) in CCl4 at -20°C; detd. by IR and (1)H NMR spectra; mixt. of Me3SbS, Me3SbCl2 and minor unidentified compd. obtained;
参考文献
Corcoran, Sarah M.; Levason, William; Patel, Rina; Reid, Gillian
Inorganica Chimica Acta, 2005 , vol. 358, # 4 p. 1263 - 1268
in neat (no solvent)
High Pressure; heating at 220-360 °C for 3 h in a rotating autoclave (1.5 l, pressure formed by react: 100 atm); apparatus and handling described;; condensation; fractionation;;
参考文献
Emeleus, H. J.; Wood, J. F.
Journal of the Chemical Society, 1948 , p. 2183 - 2188
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Gmelin Handbook: S: MVol.B3, 157, page 1863 - 1864
in not given
SbF3 was dropped into liquid SiHCl3 containing SbCl5; Purification by trap to trap distillation;
参考文献
Arthur, Neville L.; Potzinger, Peter; Reimann, Bruno; Steenbergen, H. Peter
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1989 , vol. 85, p. 1447 - 1464
in neat (no solvent)
addn. of 80 g SbF3 to a mixt. of 200 g POCl3 and 50 g SbCl5 at 75 °C and 190-200 Torr;; products contains 55 percent PF3, 5 percent POF2Cl and 40 percent POFCl2;;
参考文献
Booth, H. S.; Dutton, F. B.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2937 - 2940
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Gmelin Handbook: P: MVol.C, 212, page 487 - 489
