in neat (no solvent)
introduction of HF gas into mixture of SbCl5 and SOCl2 at common temps.; temp. decreases;; distillation (pressure/column), or passing through cooled water; washed (SbCl5/SOCl2);;
in neat (no solvent)
addn. of 80 g SbF3 to a mixt. of 200 g POCl3 and 50 g SbCl5 at 75 °C and 190-200 Torr;; products contains 55 percent PF3, 5 percent POF2Cl and 40 percent POFCl2;;
参考文献
Booth, H. S.; Dutton, F. B.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2937 - 2940
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Gmelin Handbook: P: MVol.C, 212, page 487 - 489
Sabanejew
Justus Liebigs Annalen der Chemie, 1883 , vol. 216, p. 257
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van de Walle
Bulletin des Societes Chimiques Belges, 1914 , vol. 28, p. 305
Chem. Zentralbl., 1922 , vol. 93, # III p. 339
