1: lithium / tetrahydrofuran / 36 h / -8 °C
2: 1.) copper(I) cyanide, 3.) water
View Scheme
参考文献
Fleming, Ian; Newton, Trevor W.; Roessler, Felix
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 2527 - 2532
1: dimethyl(phenyl)silyl chloride With lithium in tetrahydrofuran
T=0°C;
2: With zinc(II) chloride in tetrahydrofuran; diethyl ether
T=0°C;
3: isoprene With copper(l) iodide in tetrahydrofuran; diethyl ether
T=0°C; Further stages. Title compound not separated from byproducts.;
参考文献
Auer, Gertrud; Oestreich, Martin
Chemical Communications, 2006 , # 3 p. 311 - 313
Fleming, Ian; Henning, Rolf; Parker, David C.; Plaut, Howard E.; Sanderson, Philip E. J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 4 p. 317 - 338
1: cyclopropyl benzene With lithium; 4,4'-di-tert-butylbiphenyl in tetrahydrofuran
T=20°C; 4 h;
2: dimethyl(phenyl)silyl chloride in tetrahydrofuran
T=0°C; 0.5 h;
3: With water in tetrahydrofuran
T=0 - 20°C; 1 h;
参考文献
Gomez, Cecilia; Lillo, Victor J.; Yus, Miguel
Tetrahedron, 2007 , vol. 63, # 22 p. 4655 - 4662
