Boron tris(trifluoromethanesulfonate) in dichloromethane 2 h; Ambient temperatureother times; other solvent; other adamantyl halide; competitive reaction with benzene; Product distributionMechanism;
参考文献
Olah, George A.; Farooq, Omar; Farnia, S. Morteza F.; Wu, An-hsiang
Journal of Organic Chemistry, 1990 , vol. 55, # 5 p. 1516 - 1522
T=50°C; activation parameters (ΔH(excit.), ΔS(excit.)); rate of solvolysis at diff. temp. (16.1-70.0 deg C) for MeOH, EtOH, aq.EtOH and 2,2,2-trifluoroethanol and at 50 deg C for further 30 different solvents; Product distributionRate constant;
参考文献
Journal of Organic Chemistry, , vol. 55, # 19 p. 5394 - 5399