sodium hydroxide in water
Kinetics; mixing peroxynitrite (0.01 M NaOH) with NaI (0.2 M phosphate buffer at pH 5.8 and at pH 3.2); absorbance at 350 nm;
参考文献
Kurz, Christophe; Zeng, Xiuqiong; Hannemann, Stefan; Kissner, Reinhard; Koppenol, Willem H.
Journal of Physical Chemistry A, 2005 , vol. 109, # 6 p. 965 - 969
in neat (no solvent)
0.025 mol MoO3 and 0.025 mol NaI are mixed and heated in a silica tube at ca. 575 K in vac. (ca. 1E-3 Torr) for periods ranging from 3 to 6 h; intermediate grinding and reheatings required to ensure completion of the reaction; liberated I2 detd. quant.; Li content detd. by at. absorption spectroscopy; Mo(5+) detected by X-ray photoelectron and ESR spectroscopy; chem. anal. for Mo(5+) content;
参考文献
Ganguli; Ganapathi; Gopalakrishnan; Rao
Journal of Solid State Chemistry, 1988 , vol. 74, # 1 p. 228 - 231
in sulfur dioxide
Electrolysis; electrolyzing soln. of NaI in liquid SO2, pptn. of S on cathode, formation of Na2SO3, liberation of I2 on anode;;
参考文献
Bagster; Steele
Chem. News J. Ind. Sci., 1912 , vol. 105, p. 157 - 157
Full Text Show Details
Bagster; Steele
Chem. News J. Ind. Sci., 1912 , vol. 105, p. 169 - 169
Full Text Show Details
Gmelin Handbook: Na: MVol., 137, page 449 - 451
in acetone
pptn. of NaCl and formation of I2 by react. of a soln. of N(PCl2)3 in acetone with NaI;;
参考文献
Gmelin Handbook: P: MVol.C, 236, page 539 - 542
Full Text Show Details
Sharpe, A. G.
Paddock, N. L., Searle, H. T. in: Emeleus, H. J., Sharpe, A. G., Advances in inorganic Chemistry and Radiochemistry, Bd. 1, New York 1959, S. 347/83
in perchloric acid
Kinetics; N2-atmosphere; 25.+-.0.1°C, I=0.2 M (NaClO4), excess NaI, 1.10E-5to 5.40E-3 M HClO4; not isolated, reaction followed by UV/VIS spectroscopy;
参考文献
Dozsa, L.; Szilassy, I.; Beck, M. T.
Inorganica Chimica Acta, 1976 , vol. 17, p. 147 - 153
