2-甲基-1-苯基-丙-2-烯-1-酮合成路线 （共 105 条）
反应条件
T=210 - 230°C; P=18 - 20 Torr; 1.5 h;
参考文献
Yandovskii; Tselinskii
Russian Journal of Organic Chemistry, 1997 , vol. 33, # 2 p. 147 - 152
反应条件
1: tetrahydrofuran / 0 °C
2: 70 percent / CrO3, pyridine / CH2Cl2 / Ambient temperature
View Scheme
参考文献
Bonnert, Roger V.; Jenkins, Paul R.
Journal of the Chemical Society, Chemical Communications, 1987 , # 20 p. 1540 - 1541
反应条件
1: n-butyllithium
2: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / Reflux
3: acetic anhydride / 5 h / 80 °C / Inert atmosphere
View Scheme
参考文献
Hu, Bin; Meng, Meng; Jiang, Shanshan; Deng, Weiping
Chinese Journal of Chemistry, 2012 , vol. 30, # 6 p. 1289 - 1294
反应条件
1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / Reflux
2: acetic anhydride / 5 h / 80 °C / Inert atmosphere
View Scheme
参考文献
Hu, Bin; Meng, Meng; Jiang, Shanshan; Deng, Weiping
Chinese Journal of Chemistry, 2012 , vol. 30, # 6 p. 1289 - 1294
反应条件
sodium formate
Yield given. Yields of byproduct given;
参考文献
Creary, Xavier
Journal of the American Chemical Society, 1984 , vol. 106, # 19 p. 5568 - 5577
反应条件
in tetrahydrofuran
T=-70 - 20°C; 18 h;
参考文献
Kauffmann, Thomas; Kieper, Hansjoerg
Chemische Berichte, 1992 , vol. 125, # 4 p. 907 - 912
反应条件
sodium acetate; acetic anhydride
Yield given. Yields of byproduct given;
参考文献
Creary, Xavier
Journal of the American Chemical Society, 1984 , vol. 106, # 19 p. 5568 - 5577
参考文献
Traynelis,V.J.; Ode,R.H.
Journal of Organic Chemistry, 1970 , vol. 35, # 7 p. 2207 - 2212
反应条件
hydrogen fluoride; triethylamine in acetonitrile
anodic oxidation on graphite, potentiostatic, U = +1.9 V vs. Ag/Ag(+), charge: 2.6 F/mol; Yield given. Yields of byproduct given;
参考文献
Laurent, E.; Marquet, B; Tardivel, R.; Thiebault, H.
Bulletin de la Societe Chimique de France, 1986 , # 6 p. 955 - 964
反应条件
in various solvent(s)
T=70°C; ΔH(act.),ΔS(act.); KineticsThermodynamic dataRate constant;
参考文献
Zavalsky, Robert C.; Lisiak, Michael; Kovacic, Peter; Luedtke, Al; Timberlake, Jack W.
Tetrahedron Letters, 1980 , vol. 21, p. 425 - 428
