in diethyl ether
(Ar); to soln. of Ti complex was added threefold excess of DCl in etherat -78°C, mixt. was slowly warmed up to room temp.; solvent was decanted and residue extd. with pentane, eytt. yielded CpTiCl3, residue was extd. with CH2Cl2, yielding Cp2TiCl2; identification by spectroscopy;
参考文献
Klei, E.; Teuben, J. H.
Journal of Organometallic Chemistry, 1980 , vol. 188, # 1 p. 97 - 108
in gas
Kinetics; Irradiation (UV/VIS); investigation of kinetics of formation of SiCl3OCl and SiCl3OH: photolysis (>= 300nm) of a Cl2-SiHCl3-air-mixture in presence of DCl;; not isolated, monitoring of react. by IR;;
参考文献
Niki, H.; Maker, P. D.; Savage, C. M.; Breitenbach, L. P.; Hurley, M. D.
Journal of Physical Chemistry, 1985 , vol. 89, # 17 p. 3725 - 3729
in toluene
addn. of anhydrous DCl gas (1 equiv) to a cold (-78°C) soln. of the Zr compound, followed by warming to room temp.; removal of volatiles under vac. and extn. of the residue with pentane allows sepn. of the products; pentane removed from the resulting filtrate to afford the aldehyde which is distd.;
参考文献
Elsner,F.H.; Woo,H.G.; Tilley,T.D.
Journal of the American Chemical Society, 1988 , vol. 110, p. 313
in water-d2
treatment of NaH2PO2*H2O with DCl in D2O under Ar, stirring for 1 h, removal of solvent in vacuo, adding D2O and DCl, stirring for addnl. 30 min; not isolated;
参考文献
Yorimitsu; Shinokubo; Oshima
Bulletin of the Chemical Society of Japan, 2001 , vol. 74, # 2 p. 225 - 235
in neat (no solvent)
exclusion of moisture; condensation of HCl to Sn-compd., warming (20°C, 24 h); removal of volatiles (vac.), products not sepd.; IR-spectroscopy;
参考文献
Haas, Alois; Wingender, Norbert
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1989 , vol. 576, p. 151 - 159
