1-邻十六基-2-邻乙酰基-sn-甘油合成路线 （共 15 条）
反应条件
1: POCl3, Et3N / CHCl3 / 0.5 h / 0 °C 2: pyridine / CHCl3 / 14 h / Ambient temperature View Scheme
参考文献
Chemistry Letters, , # 8 p. 1417 - 1420
参考文献
Tetrahedron Letters, , vol. 34, # 21 p. 3463 - 3466
反应条件
CCL (Yeast); triethylamine 1.) CHCl3, RT, 5 h, 2.) heptane, n-BuOH, RT, 20 h; Yield given. Multistep reaction;
参考文献
Synthetic Communications, , vol. 21, # 17 p. 1763 - 1768
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane; water
T=20°C; 4 h;
参考文献
Tsuboi, Sadao; Takeda, Shinji; Yamasaki, Yasuhisa; Sakai, Takashi; Utaka, Masanori; et al.
Chemistry Letters, 1992 , # 8 p. 1417 - 1420
反应条件
boric acid; silica gel in diethyl ether; Petroleum ether
参考文献
Boeckel, C. A. A. van; Marel, G. A. van der; Westerduin, P.; Boom, J. H. van
Synthesis, 1982 , # 5 p. 399 - 402
反应条件
1: NaH
2: LiAlH4
4: pyridine
5: silica gel, boric acid / petroleum ether
View Scheme
参考文献
Kumar; Bhakuni
Tetrahedron Letters, 1993 , vol. 34, # 21 p. 3463 - 3466
反应条件
2: pyridine
3: silica gel, boric acid / petroleum ether
View Scheme
参考文献
Kumar; Bhakuni
Tetrahedron Letters, 1993 , vol. 34, # 21 p. 3463 - 3466
反应条件
1: pyridine
2: silica gel, boric acid / petroleum ether
View Scheme
参考文献
Kumar; Bhakuni
Tetrahedron Letters, 1993 , vol. 34, # 21 p. 3463 - 3466
反应条件
1: 92 percent / Et3N*3HF / 2 h / 80 °C
2: 100 percent / pyridine; MeOH / tetrahydrofuran / 3 h / 20 °C
View Scheme
参考文献
Stamatov, Stephan D.; Kullberg, Martin; Stawinski, Jacek
Tetrahedron Letters, 2005 , vol. 46, # 40 p. 6855 - 6859
反应条件
1: NaH / dimethylformamide / 24 h / 20 °C
2: HCl aq. / methanol / 2 h / Heating
3: 75 percent / pyridine; tetrahydrofuran / 2 h / Ambient temperature
4: 100 percent / pyridine / 40 h / 20 °C
5: 80 percent / Boric acid / Silicic acid column / diethyl ether; petroleum ether
View Scheme
参考文献
Boeckel, C. A. A. van; Marel, G. A. van der; Westerduin, P.; Boom, J. H. van
Synthesis, 1982 , # 5 p. 399 - 402
