potassium permanganate

1: molecular sieves 4A / diethyl ether / 112 h 2: diethyl ether / 1 h / Heating 3: 15percent aq KMnO4, 5 N HCl / Ambient temperature View Scheme

1: diethyl ether / 1 h / Heating 2: 15percent aq KMnO4, 5 N HCl / Ambient temperature View Scheme

1: molecular sieves 4A / diethyl ether / 112 h 2: diethyl ether / 1 h / Heating 3: 15percent aq KMnO4, 5 N HCl / Ambient temperature View Scheme

oxygen; tetrasodium ethylenediaminetetraacetate; iron(II) sulfate; isoascorbic acid in water T=37°C; 1 h; sodium phosphate buffer; var. reag.: Fe(III)TPPCl with iodosylxylene, or cumenehydroperoxide or O2/Zn/AcOH; Yield given. Further byproducts given;

perchloric acid; iron(II) diperchlorate; dihydrogen peroxide in water; acetonitrile T=37°C; 1 h; var. reag.: O2 and ascorbic acid; Fe(III)TPPCl and iodosylxylene or cumene hydroperoxide;Fe(III)TPPCl,O2 and Zn, AcOH; liver microsomes and NADPH, O2; Product distribution;

N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline in tetrahydrofuran 72 h; Ambient temperature;