in neat (no solvent)
introduction of HF gas into mixture of SbCl5 and SOCl2 at common temps.; temp. decreases;; distillation (pressure/column), or passing through cooled water; washed (SbCl5/SOCl2);;
Holloway, John H.; Staunton, Garry M.; Rediess, Klaus; Bougon, Roland; Brown, David
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 2163 - 2166
in neat (no solvent)
dropping IF5 to SOCl2 at room temp.;; condensation (cooling by liquid air); removal of ICl3 and Cl2 by Hg (shaking); fractionation;;
参考文献
Jonas, H.
Z. Anorg. Chem., 1951 , vol. 265, p. 273 - 283
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Gmelin Handbook: S: MVol.B3, 157, page 1863 - 1864
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Jonas, H.
in: FIAT Review, Bd. 23, S. 192
HF and NSF3 were condesed in Kel-F reactor at -196°C, allowed toreact at room temp. overnight, SOCl2 added, reacted at room temp. for 2weeks and volatile products were condensed into a NaF scrubber; fractionation through a series of traps at -10, -78, and -196°C in vac., a -78°C trap contained the product, distillation;
参考文献
Thrasher, Joseph S.; Hosmane, Narayan S.; Naurer, Donald E.; Clifford, Alan F.
Inorganic Chemistry, 1982 , vol. 21, p. 2506 - 2508
