in neat (no solvent) dark electric discharge in a mixture of gaseous PCl3 and H2; formation of a scarlet-red pptn. and a colorless liquid with a yellow compound suspended in it;; filtration, distn. of the filtrate; crystn. of a white mass on cooling;;
参考文献
Besson, A.; Fournier, L.
C. r. Acad. Sci. (Paris), 1910 , vol. 150, p. 102 - 104
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Gmelin Handbook: P: MVol.C, 179, page 412 - 414
in neat (no solvent) Electric Arc; react. of Zn with PCl3 in an atmosphere of N2 under influence of a Zn arc; react. of Zn with PCl3 forming ZnCl2 and P and by-react. of Zn with PCl3 forming ZnCl2 and P2Cl4;;
参考文献
Gmelin Handbook: P: MVol.C, 185, page 427 - 429
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Stock, A.; Brandt, A.; Fischer, H.
Ber. dtsch. chem. Ges., 1925 , vol. 58, p. 643 - 657
in neat (no solvent) heating a mixt. of PCl3 and PBr3 with S in a sealing tube at 190 °C;; fractionation at 20 Torr;;
参考文献
Delwaulle, M.-L.; Francois, F.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1947 , vol. 224, p. 1422 - 1423
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Gmelin Handbook: P: MVol.C, 263, page 602 - 605
in neat (no solvent) passing a stream of H2S over a mixt. of PCl3 and PBr5;; product poluted with a small amount of bromine; removal of Br2 on shaking with Hg; fractionation at reduced pressure;;
参考文献
Delwaulle, M.-L.; Francois, F.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1947 , vol. 224, p. 1422 - 1423
Full Text Show Details
Gmelin Handbook: P: MVol.C, 263, page 602 - 605
