2-苯基-1,3-二恶烷合成路线 （共 72 条）
反应条件
lithium aluminium tetrahydride; (η5-C5H5)titanium trichloride in diethyl ether 12 h; Heating; Title compound not separated from byproducts;
参考文献
Shaozu, Wu; Yin, Chen; Yulan, Zhang
Bulletin des Societes Chimiques Belges, 1991 , vol. 100, # 5 p. 421 - 424
参考文献
Eliel; Badding
Journal of the American Chemical Society, 1959 , vol. 81, p. 6087
反应条件
trifluorormethanesulfonic acid T=110°C; 7 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Fukuzawa, Shin-Ichi; Tsuchimoto, Teruhisa; Hiyama, Tamejiro
Journal of Organic Chemistry, 1997 , vol. 62, # 1 p. 151 - 156
反应条件
copper(II) sulfate in benzene T=80°C; Insertion;
参考文献
Zenkevich; Kharicheva; Kostikov
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 11 p. 1567 - 1573
反应条件
triethylsilane; acetyl-bromide; stannous bromide in dichloromethane 3 h; Ambient temperature;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 64, # 4 p. 1410 - 1412
反应条件
1: N-bromosuccinmide / benzene / 1 h / 20 - 50 °C / |Inert atmosphere; |Schlenk technique; |Irradiation 2: sodium iodide / benzene / 1 h / 20 - 50 °C / |Inert atmosphere; |Schlenk technique; |Irradiation View Scheme
参考文献
Levin, Vitalij V.; Zemtsov, Artem A.; Struchkova, Marina I.; Dilman, Alexander D.
Organic Letters, 2013 , vol. 15, # 4 p. 917 - 919
反应条件
trifluorormethanesulfonic acid 10 h; Heating;
参考文献
Journal of Organic Chemistry, , vol. 62, # 1 p. 151 - 156
参考文献
Journal of Organic Chemistry, , vol. 62, # 1 p. 151 - 156
反应条件
copper(II) sulfate in benzene T=80°C; Insertion;
参考文献
Zenkevich; Kharicheva; Kostikov
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 11 p. 1567 - 1573
反应条件
1: 89 percent / 1.)diisobutylaluminum hydride, 2.)methanol / toluene / Ambient temperature 2: oxalyl chloride - DMSO, Et3N / CH2Cl2 / 0.75 h / -70 - -65 °C 3: 181.2 g / CH2Cl2 / 1.)-70 -> -65 deg C, 15 min., 2.)r.t., 4 h View Scheme
参考文献
Martinelli, Michael J.
Journal of Organic Chemistry, 1990 , vol. 55, # 17 p. 5065 - 5073
