aluminium in solid byproducts: O2; Pr6O11, AlBr3 (Ln:Al = 1:4) and Al powder were placed into an one-end sealed quartz tube under Ar, sealed under vac., heated at 600 K for 1 h; sealed tube was placed in a tubular furnace with a reduced temp. gradient from 750 to 460 K, vapor transport reaction for 6 h, tube was quicklyremoved from the furnace, the hot end was quenched with water, AlBr3 wa s condensed;
参考文献
Wang, Zhi-Chang; Yu, Jin
Inorganic Chemistry, 2007 , vol. 46, # 10 p. 4248 - 4255
tetrahydrofuran in tetrahydrofuran molar ratio B:Al=2.8:1 to 1:2; not isolated, detd. by (11)B-NMR spectroscopy;
参考文献
Bakum, S. I.; Bolotina, I. V.; Kuznetsova, S. F.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1994 , vol. 39, p. 1119 - 1128
Zhurnal Neorganicheskoi Khimii, 1994 , vol. 39, p. 1173 - 1183
aluminium in solid Ln2O3, AlBr3 (Ln:Al = 1:4) and Al powder were placed into an one-end sealed quartz tube under Ar, sealed under vac., heated at 600 K for 1 h; sealed tube was placed in a tubular furnace with a reduced temp. gradient from 750 to 460 K, vapor transport reaction for 6 h, tube was quicklyremoved from the furnace, the hot end was quenched with water, AlBr3 wa s condensed;
参考文献
Wang, Zhi-Chang; Yu, Jin
Inorganic Chemistry, 2007 , vol. 46, # 10 p. 4248 - 4255
in further solvent(s) byproducts: ((C6H2(CH3)3)3PBr)[AlBr4]; in bromobenzene; stirred rapidly for 2 d at 25°C; vapor diffusion of cyclohexane into soln.;
参考文献
Menard, Gabriel; Stephan, Douglas W.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 36 p. 8396 - 8399
