三氯一氧化钒 三氯代氧化钒(V)合成路线 （共 117 条）
反应条件
in neat (no solvent)
参考文献
Emeleus, H. J.; Gutmann, V.
Journal of the Chemical Society, 1949 , p. 2979 - 2982
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Gmelin Handbook: V: MVol.B1, 90, page 243 - 246
反应条件
in neat (no solvent) byproducts: NaCl; on-line process; gaseous VOCl3 passed over solid NaF heated to 375°C; gaseous NaCl and VOF3 obtained; detd. by IR spectroscopy;
参考文献
Zidan, Mohammed D.; Allaf, Abdul W.
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2000 , vol. 56, # 14 p. 2693 - 2698
反应条件
in tetrachloromethane
参考文献
Gmelin Handbook: V: MVol.B1, 91, page 246 - 247
反应条件
in toluene (N2); standard Schlenk technique; VOCl3 (2 equiv.) added dropwise to VO(Oi-Pr)3 in toluene (1 equiv.); solvent removed in vac.; residue stripped (pentane); flash distd.;
参考文献
Hagen, Henk; Bezemer, Chris; Boersma, Jaap; Kooijman, Huub; Lutz, Martin; Spek, Anthony L.; Van Koten, Gerard
Inorganic Chemistry, 2000 , vol. 39, # 18 p. 3970 - 3977
反应条件
in hexane i-PrOH added dropwise to VOCl3 in hexane while N2 bubbled into the react. mixt. at room temp.; complex distd. under reduced pressure;
参考文献
Martinez, Fernando; Campo, Carmen del; Llama, Emilio F.
Journal of the Chemical Society, Perkin Transactions 1, 2000 , p. 1749 - 1752
反应条件
(C2H5)3N in toluene
(Ar); MeOH added to a soln. of VOCl3 at 80°C, reacted for 10 min,(C2H5)3N added, stirred at 80°C for 15 min, annealed to room tem p., stirred for 1 h; evapd. (vac.), sublimed at 60°C (vac.);
参考文献
Hoppe, Elke; Limberg, Christian; Ziemer, Burkhard
Inorganic Chemistry, 2006 , vol. 45, # 20 p. 8308 - 8317
反应条件
in diethyl ether
recrystn. from pentane;
参考文献
Schroeder, Detlef; Loos, Jessica; Engeser, Marianne; Schwarz, Helmut; Jankowiak, Hans-Christian; Berger, Robert; Thissen, Roland; Dutuit, Odile; Doebler, Jens; Sauer, Joachim
Inorganic Chemistry, 2004 , vol. 43, # 6 p. 1976 - 1985
反应条件
in sulfuryl dichloride
react. of a soln. of VOCl3 with a soln. of SO3 - both dissolved in SO2Cl2;;
参考文献
Gmelin Handbook: S: MVol.B1, 165, page 363 - 365
反应条件
in hexane
byproducts: SO2; Sonication; (Ar) VOCl3 in hexane at room temp. was added to soiln. t-BuNSO in hexane, refluxed for 2 h; volatiles were removed in vacuo at 20°C, residue was suspnd. in pentane by sonication and kept at -80°C for 24 h, ppt. was decanted, washed with chilled pentane and dried in vacuo;
参考文献
Rufanov, Konstantin A.; Kipke, Jennifer; Sundermeyer, Joerg
Dalton Transactions, 2011 , vol. 40, # 9 p. 1990 - 1997
反应条件
in pentane
byproducts: H2O; under Ar; slow addn. of amine soln. to dissolved VOCl3 under stirring at -78°C; stirred for 30 min; removing of ice bath; further stirring until reaction mixture was warmed up to 25°C; filtration of (NH3-t-bu-(VOCl3)2O); washed (CH2Cl2 and n-pentane); dried under vac.; solvent removed from mother liquor under vacuo; sublimation of residue (80°C, high vac.); elem. anal.; NMR; IR;
参考文献
Preuss, Fritz; Fuchslocher, Edith; Leber, Edith; Towae, Willi
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1989 , vol. 44, # 3 p. 271 - 277
