三氯一氧化钒 三氯代氧化钒(V)合成路线 （共 117 条）
反应条件
in benzene byproducts: HCl; mixing VOCl3 and phenol, refluxing in benzene for a few hours; sepn. of product, filtn. of contact with air, washing with benzene followed by hexane, drying in vacuo at 40°C, elem. anal.;
参考文献
Joseph, K.; Deshpande, S. S.; Gopinathan, Sarada; Gopinathan, C.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1983 , vol. 22, # 2 p. 159 - 160
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 332, p. 189 - 196
参考文献
Loutfy, Rafik O.
Canadian Journal of Chemistry, 1981 , vol. 59, p. 549 - 554
反应条件
ethanol; ammonia in hexane byproducts: NH4Cl; Ar-atmosphere; dropwise addn. of soln. of VOCl3 (cooling, stirring) to soln. of EtOH in hexane; NH3 passed through obtained soln. until no more NH4Cl was pptd.; isolation by vac. distn.; elem. anal.;
参考文献
Magomedov, G. K.-I.; Morozova, L. V.; Kusainova, K. M.; Blokhina, E. I.; Medvedeva, A. V.; Beletskaya, I. P.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 1582 - 1584
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 1777 - 1780
反应条件
ethanol in hexane byproducts: NH(C2H5)2HCl; Ar-atmosphere; dropwise addn. of soln. of VOCl3 (cooling, stirring) to soln. of EtOH in hexane; addn. of diethylamine to obtained soln. until no more NH(Et)2HCl was pptd.; isolation by vac. distn.; elem. anal.;
参考文献
Magomedov, G. K.-I.; Morozova, L. V.; Kusainova, K. M.; Blokhina, E. I.; Medvedeva, A. V.; Beletskaya, I. P.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 1582 - 1584
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 1777 - 1780
反应条件
ethanol in hexane Ar-atmosphere; dropwise addn. of soln. of VOCl3 (cooling) to soln. of EtOH and CO(NH2)2 in hexane; elem. anal.;
参考文献
Magomedov, G. K.-I.; Morozova, L. V.; Kusainova, K. M.; Blokhina, E. I.; Medvedeva, A. V.; Beletskaya, I. P.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 1582 - 1584
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 1777 - 1780
反应条件
ethanol in hexane Ar-atmosphere; dropwise addn. of soln. of VOCl3 (cooling) to soln. of EtOH and SC(NH2)2 in hexane; ppt. washed with hexane and vacuum-dried; elem. anal.;
参考文献
Magomedov, G. K.-I.; Morozova, L. V.; Kusainova, K. M.; Blokhina, E. I.; Medvedeva, A. V.; Beletskaya, I. P.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 1582 - 1584
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 1777 - 1780
参考文献
Gmelin Handbook: V: MVol.B1, 91, page 246 - 247
参考文献
Gmelin Handbook: V: MVol.B1, 91, page 246 - 247
反应条件
in not given at ambiente temp.;;
参考文献
Gmelin Handbook: V: MVol.B1, 90, page 243 - 246
Full Text Show Details
Dehnicke, K.; Afify, M.
Dehnicke, K. (Angew. Chem. 77 (1965) 22/9)
