triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane in 1,4-dioxane T=80°C; Borylation; 16 h; Title compound not separated from byproducts;
1: methyllithium With indium(III) chloride in tetrahydrofuran T=-78 - 20°C; 2: 4-tert-butyl-1-cyclohexen-1-yl trifluoromethanosulfonate With bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran 7 h; Heating; Further stages.;
参考文献
Perez, Ignacio; Sestelo, Jose Perez; Sarandeses, Luis A.
Organic Letters, 1999 , vol. 1, # 8 p. 1267 - 1269
1: PhX (X = Li or MgBr) With indium(III) chloride in tetrahydrofuran T=-78 - 20°C; 2: carbon monoxide; 4-tert-butyl-1-cyclohexen-1-yl trifluoromethanosulfonate With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=70°C; P=1900 Torr; 3 h;
参考文献
Pena, Miguel A.; Perez Sestelo, Jose; Sarandeses, Luis A.
Synthesis, 2003 , # 5 p. 780 - 784
triphenyl-arsane; tris-(dibenzylideneacetone)dipalladium(0) in various solvent(s) Ambient temperatureand with LiCl; relative rates of the two transmetalation reactions; Product distribution;
参考文献
Farina, Vittorio; Krishnan, Bala; Marshall, Daniel R.; Roth, Gregory P.
Journal of Organic Chemistry, 1993 , vol. 58, # 20 p. 5434 - 5444
