in further solvent(s) byproducts: (FCN)3; reactn. of a soln. of dirhodane in FCl2C-CClF2 with diluted F2 (F2:N2 0 1:10); cooled down to -183°C; solvent removed by condensation; mixt. condensed to aq. KOH-soln. at room temp. to remove SF4, SOF and (FCN)3; sepn. by fractionated condensation at -127°C, -140°C, -196°C;
in neat (no solvent) Ensemble of MoTe2 on W-saucer with small quantities of S, resting on a perfluorinated Ni-crucible, is combusted with F2 in a calorimeter bomb.; Gases are condensed into a trap (liq. N2).;
参考文献
Journal of Chemical Thermodynamics, , vol. 21, # 7 p. 701 - 708
S2NAsF6 supported on Ni-crucibles reacted spontaneously with F2 at ca. 0.2 MPa; Products were condensed into a liquid-N2-cooled trap and after gasification expanded into a Monel cell. IR-spect. detn.;
参考文献
Journal of Chemical Thermodynamics, , vol. 21, # 2 p. 153 - 158
