byproducts: SSF2; the sepd. fluorine and COS in a high vac. app., cooling to -196°C and -78°C, resp., after the react. cooling the gas to -196°C, further byproducts; continuous evapn. of CO; condensation, cooling to -78°C, evapn. of volatile compds. for 0.5 h, detected by IR;
参考文献
Haas, A.; Willner, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1980 , vol. 462, p. 57 - 60
Fowler, R. D.; Anderson, H. C.; Hamilton, J. M.; Burford, W. B.; Spadetti, A.; et al.
Industrial and Engineering Chemistry, 1947 , vol. 39, p. 343 - 345
in neat (no solvent) fluorination of powder mixt. of Mo and MgF2 in molar ratio 2 : 1; distn. (vac.);
参考文献
Khaldoyanidi, K. A.; Yakovlev, I. I.; Ikorskii, V. N.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1981 , vol. 26, p. 1639 - 1640
Zhurnal Neorganicheskoi Khimii, 1981 , vol. 26, p. 3067 - 3069
in neat (no solvent) Ensemble of MoTe2 on W-saucer with small quantities of S, resting on a perfluorinated Ni-crucible, is combusted with F2 in a calorimeter bomb.; Gases are condensed into a trap (liq. N2).;
参考文献
O'Hare, P. A. G.; Hope, G. A.
Journal of Chemical Thermodynamics, 1989 , vol. 21, # 7 p. 701 - 708
