trifluorophosphane合成路线 （共 187 条）
反应条件
in dichloromethane
Sonication; not isolated, detected by NMR;
参考文献
Koechner, Tobias; Engesser, Tobias A.; Scherer, Harald; Plattner, Dietmar A.; Steffani, Alberto; Krossing, Ingo
Angewandte Chemie - International Edition, 2012 , vol. 51, # 26 p. 6529 - 6531
反应条件
in further solvent(s)
excess of PF2I, in Si(CH3)4; detected by NMR spectroscopy;
参考文献
Demuth, R.; Grobe, J.
Journal of Fluorine Chemistry, 1972 , vol. 2, p. 299 - 314
反应条件
in not given
react. with hot KMnO4 soln.;;
参考文献
Voznesenskii, S. A.; Dubnikov, L. M.
Zh. obshch. Khim., 1941 , vol. 11, p. 507 - 517
C. II, 1941 , p. 1721
参考文献
O'Donnell, T. A.; Stewart, D. F.; Wilson, P. W.
Inorganic Chemistry, 1966 , vol. 5, p. 1438 - 1441
反应条件
in benzene-d6
solution of Au(PF3)Cl in C6D6 hold in glass vessel exposed to daylight for 7 day;
参考文献
Schoedel, Frauke; Bolte, Michael; Wagner, Matthias; Lerner, Hans-Wolfram
Zeitschrift fur Anorganische und Allgemeine Chemie, 2006 , vol. 632, # 4 p. 652 - 654
反应条件
in monofluoro-trichloromethane; benzene-d6
product mixt. not sepd., detd. by NMR spectroscopy;
参考文献
Arnold, David E. J.; Cromie, Ernest R.; Rankin, David W. H.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 1999 - 2004
反应条件
in not given
react. with FSO2NO; formation of NO(PF6), NO, NOCl, SO2 and PF3;;
参考文献
Seel, F.; Massat, H.
Z. anorg. allg. Chem., 1955 , vol. 280, p. 186 - 196
反应条件
in not given
react. with an excess of MoF6 forming PF3, MoCl5 and Cl2; react. of MoCl5 forming MoCl4 and Cl2; further react. of MoF6 with PF3 forming PF5 and MoF5;;
参考文献
O'Donnell, T. A.; Stewart, D. F.
Journal of Inorganic and Nuclear Chemistry, 1962 , vol. 24, p. 309 - 314
反应条件
in acetonitrile
byproducts: PF5*CH3CN; fluoride to P molar ratio from 1:1 to 2:1, a soln. of P compd. frozen inliq. N2, ftoride added, gradually heated, or reacted at room temp.; soln. separated, not isolated, detected by NMR;
参考文献
Kokunov; Ershova; Razgonyaeva
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2002 , vol. 28, # 7 p. 461 - 463
反应条件
in acetonitrile
byproducts: PF5*CH3CN; fluoride to P molar ratio from 1:1 to 2:1, a soln. of P compd. frozen inliq. N2, ftoride added, gradually heated, or reacted at room temp.; soln. separated, not isolated, detected by NMR;
参考文献
Kokunov; Ershova; Razgonyaeva
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2002 , vol. 28, # 7 p. 461 - 463
