trifluorophosphane合成路线 （共 187 条）
反应条件
in neat (no solvent) reaction at red heat after a period of 30 min.;;
参考文献
Ann. Chim. Phys., , vol. 6, p. 433 - 467
Si: MVol.B, 47, page 121 - 123
反应条件
in neat (no solvent) react. at >100°C and 50-100 atm in a pressure pipe;;
参考文献
Gmelin Handbook: P: MVol.C, 171, page 393 - 395
反应条件
in neat (no solvent) byproducts: HF; heating with gaseous HCl;;
参考文献
Moissan, H.
Ann. Chim. Phys., 1885 , vol. 6, p. 433 - 467
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Gmelin Handbook: P: MVol.C, 171, page 393 - 395
反应条件
in gas High Pressure; PF3 and SF6 (molar ratio 1.1:1) condences into gold tube at -196°C, sealed, held for 24 h at 541°C (1333 atm) or at 580°C (567 atm); detected by IR spectra;
参考文献
Hagen, Arnulf P.; Terrell, Donald L.
Inorganic Chemistry, 1981 , vol. 20, p. 1325 - 1326
反应条件
in neat (no solvent) condensing PF3 onto BiF5, heating to 80°C for 5 days;
参考文献
Chen, Grace S. H.; Passmore, Jack
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1251 - 1256
反应条件
in solid matrix Irradiation (UV/VIS); reaction of titanium ablated atoms with phosphorus trifluoride in Ar with condensation at 8 K for 60 min, irradiation at 290 mn for 20 min, irradiation at >220 nm for 20 min; IR monitoring;
参考文献
Wang, Xuefeng; Lyon, Jonathan T.; Andrews, Lester
Inorganic Chemistry, 2009 , vol. 48, # 13 p. 6297 - 6302
反应条件
in neat (no solvent) Irradiation (UV/VIS); U reacted with PF3 under Ar at 4 K for 60 min, irradiated for 20 min, annealed to 20, 30 K; monitored by IR;
参考文献
Andrews, Lester; Wang, Xuefeng; Lindh, Roland; Roos, Bjoern O.; Marsden, Colin J.
Angewandte Chemie - International Edition, 2008 , vol. 47, # 29 p. 5366 - 5370
反应条件
in neat (no solvent) Irradiation (UV/VIS); photolysis (water filtered high pressure mercury arc); identified by IR spectroscopy;
参考文献
Andrews, Lester; Withnall, Robert
Inorganic Chemistry, 1989 , vol. 28, p. 494 - 499
参考文献
Gmelin Handbook: U: SVol.C8, 5.1.5.3, page 139 - 163
反应条件
in hydrogen fluoride reaction in anhydrous HF below room temp.; powder XRD;
参考文献
Burns, R. C.; O'Donnell, T. A.; Randall, C. H.
Journal of Inorganic and Nuclear Chemistry, 1981 , vol. 43, p. 1231 - 1238
