trifluorophosphane合成路线 （共 187 条）
反应条件
in gas
byproducts: NiC6H5CHO(1+), NiC6H5CH2OH(1+); The react. is performed on an ion cyclotron resonance (ICR) mass spectrometer. The nickel ion and the aromatic compd. are admitted to the ICR cell in approx. 1:1 ratio, to a total pressure of 6E-6 Torr.; MS;
参考文献
Stepnowski, Richard; Allison, John
Journal of the American Chemical Society, 1989 , vol. 111, # 2 p. 449 - 457
反应条件
in gas
byproducts: NiC6H5CH3(1+), NiC6H5COCH3(1+); The react. is performed on an ion cyclotron resonance (ICR) mass spectrometer. The nickel ion and the aromatic compd. are admitted to the ICR cell in approx. 1:1 ratio, to a total pressure of 6E-6 Torr.; MS;
参考文献
Stepnowski, Richard; Allison, John
Journal of the American Chemical Society, 1989 , vol. 111, # 2 p. 449 - 457
反应条件
in gas
byproducts: NiC6H5CH3(1+), NiC6H5CH2CHO(1+); The react. is performed on an ion cyclotron resonance (ICR) mass spectrometer. The nickel ion and the aromatic compd. are admitted to the ICR cell in approx. 1:1 ratio, to a total pressure of 6E-6 Torr.; MS;
参考文献
Stepnowski, Richard; Allison, John
Journal of the American Chemical Society, 1989 , vol. 111, # 2 p. 449 - 457
反应条件
in gas
byproducts: NiC6H5CHNH(1+), NiC6H5CH2NH2(1+); The react. is performed on an ion cyclotron resonance (ICR) mass spectrometer. The nickel ion and the aromatic compd. are admitted to the ICR cell in approx. 1:1 ratio, to a total pressure of 6E-6 Torr.; MS;
参考文献
Stepnowski, Richard; Allison, John
Journal of the American Chemical Society, 1989 , vol. 111, # 2 p. 449 - 457
反应条件
antimony pentachloride in neat (no solvent)
byproducts: PFCl2, PF2Cl; react. of water free HF with PCl3 in a Fe-vessel;; passing the formed PF3 through wash bottles with H2O; distn. over P2O5; fractionation;;
参考文献
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in neat (no solvent)
fluorination with CaF2 at 200°C;;
参考文献
Booth, H. S.; Frary, S. G.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2934 - 2937
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Gmelin Handbook: P: MVol.C, 216, page 496 - 498
反应条件
in neat (no solvent)
passing POCl3 vapor over CaF2 heated at 150 °C;; products contains 35 percent PF3, 25 percent POF2Cl and 40 percent POFCl2;;
参考文献
Booth, H. S.; Dutton, F. B.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2937 - 2940
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Gmelin Handbook: P: MVol.C, 212, page 487 - 489
反应条件
in tetrahydrofuran
under N2, various temps.;
参考文献
Stahl,L.; Ernst,R.D.
Journal of the American Chemical Society, 1987 , vol. 109, p. 5673
反应条件
in neat (no solvent)
heating P3N5 at 710 °C on passing in gaseous CF3SF5; flushing with N2 before and after react.; cooling the receivers with dry ice-actone;; fractional vac. distn.;;
参考文献
Mao, T. J.; Dresdner, R. D.; Young, J. A.
Journal of the American Chemical Society, 1959 , vol. 81, p. 1020 - 1021
反应条件
in gas
byproducts: NiC6H5CH2Br(1+); The react. is performed on an ion cyclotron resonance (ICR) mass spectrometer. The nickel ion and the aromatic compd. are admitted to the ICR cell in approx. 1:1 ratio, to a total pressure of 6E-6 Torr.; MS;
参考文献
Stepnowski, Richard; Allison, John
Journal of the American Chemical Society, 1989 , vol. 111, # 2 p. 449 - 457
