antimony pentachloride in neat (no solvent)
High Pressure; heating a mixture of SO2Cl2, SbF3 and SbCl5 in a steel flask at 300°C (pressure formed by react.: 8 atm); apparatus and handling described;; condensation; fractionation;;
参考文献
Booth, H. S.; Herrmann, C. V.
Journal of the American Chemical Society, 1936 , vol. 58, p. 63 - 66
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Gmelin Handbook: S: MVol.B3, 157, page 1863 - 1864
in neat (no solvent)
High Pressure; reacting SbF3 and Cl2 in a autoclave at > 240°C; addn. of SO2Cl2; heating again at 240°C in an autoclave;;
参考文献
Emeleus, H. J.; Wood, J. F.
Journal of the Chemical Society, 1948 , p. 2183 - 2188
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Gmelin Handbook: S: MVol.B3, 157, page 1863 - 1864
antimony pentachloride in neat (no solvent)
High Pressure; rotating autoclav (7h/260°C/100 atm);; fractionating;;
参考文献
Emeleus, H. J.; Wood, J. F.
Journal of the Chemical Society, 1948 , p. 2183 - 2188
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Gmelin Handbook: S: MVol.B3, 91, page 1729 - 1730
in neat (no solvent)
High Pressure; heating at 220-360 °C for 3 h in a rotating autoclave (1.5 l, pressure formed by react: 100 atm); apparatus and handling described;; condensation; fractionation;;
参考文献
Emeleus, H. J.; Wood, J. F.
Journal of the Chemical Society, 1948 , p. 2183 - 2188
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Gmelin Handbook: S: MVol.B3, 157, page 1863 - 1864
SbF5 in neat (no solvent)
react. of (Ni(PCl3)4) with SBF3 in presence of catalytic amt. of SbF5;;
参考文献
Wilkinson, G.
Am. Chem. Soc., 1951 , vol. 73, p. 5501 - 5502
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Gmelin Handbook: Ni: MVol.C1, 3, page 11 - 13
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Wilkinson, G.
N. S. A., NP-1857 (1951) 1/173 1951 , vol. 5, p. 4093
antimony(V) pentachloride in neat (no solvent)
byproducts: SiH4, HCl; at room temp. for 3 h; products distd. through two traps (-93°C, toluene slush, -130°C pentane slush), the second trap containing HSiF3 was isolated, evacuated for 30 min at -130°C (1.0 torr) to remove SiH4, HCl;
in neat (no solvent)
byproducts: H2; reaction in presence of SbCl5 at room temperature;;
参考文献
Emeleus, H. J.; Maddock, A. G.
Journal of the Chemical Society, 1944 , p. 293 - 296
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Gmelin Handbook: Si: MVol.B, 233, page 635 - 638
in neat (no solvent)
fluorination of SiH2Cl2 with SbF3 at room temp. for a longer period of time;;
参考文献
Emeleus, H. J.; Maddock, A. G.
Journal of the Chemical Society, 1944 , p. 293 - 296
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Gmelin Handbook: Si: MVol.B, 233, page 635 - 638
