in neat (no solvent) ClOSO2F trasferred under vac. to FEP reactor fitted with stainless-steel valve and held at -196°C, SF4 condensed, reactor placed in bath at -90°C and allowed to warm to -40°C for 4 h; reactor cooled to -70°C, volatile materials(SF5Cl) removed, reactor warmed to -40°C and then - to 23°C and held under dynamic vac. for 10 min;
参考文献
O'Brien, Brian A.; DesMarteau, Darryl D.
Inorganic Chemistry, 1984 , vol. 23, p. 644 - 648
